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Preparation of Novel Push-Pull Benzothiazole Derivatives with Reverse Polarity: Compounds with Potential Non-Linear Optic Application
| Content Provider | Scilit |
|---|---|
| Author | Hrobárik, Peter Zahradník, Pavol Sigmundová, Ivica |
| Copyright Year | 2004 |
| Description | The hitherto unknown 6-dimethylaminobenzothiazole-2-carbaldehyde was prepared as a starting compound for the synthesis of novel push-pull benzothiazole derivatives with reverse polarity. These compounds are substituted at the 2-position by strong electron-acceptor groups and at the 6-position by $NMe_{2}$ as strong electron-donor. The new method for synthesis of 6-dimethylaminobenzothiazole involved the successful use of sonochemical reductive methylation. Expected non-linear optical properties of target molecules were studied by EFISH method. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2004-837309.pdf |
| Ending Page | 604 |
| Page Count | 5 |
| Starting Page | 600 |
| ISSN | 00397881 |
| e-ISSN | 1437210X |
| DOI | 10.1055/s-2004-837309 |
| Journal | Synthesis |
| Issue Number | 04 |
| Volume Number | 2005 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2004-12-22 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synthesis Organic Chemistry Non-linear Optics Hyperpolarizability |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
