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Reaction of Linear Push-Pull Enamines at the β′-Position
| Content Provider | Scilit |
|---|---|
| Author | Kostyuk, Aleksandr N. Volochnyuk, Dmitriy M. Sibgatulin, Dmitriy A. |
| Copyright Year | 2007 |
| Description | Enamine tautomerism is often the main cause of regioselectivity problems in the chemistry of enamines derived from ketones. Linear push-pull tertiary enamines featuring a methyl (methylene) group at the α-position do not experience such tautomerism; nevertheless, a number of reactions proceed with participation of the methyl (methylene) group. It was our objective to analyze all known reactions of this type and show their high synthetic potential. 1 Introduction 2 Electrophilic Functionalization of Preformed Lithiated or Silylated Enamines 3 Uncatalyzed Reactions of Monoelectrophilic Reagents at the Methyl (Methylene) Group 4 Reactions Proceeding at Both the β- and β′-Carbon of the Enamine 5 Reactions Proceeding at the α-Methyl (Methylene) Group and β-Functional Group 6 Conclusion |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2007-1000848.pdf |
| Ending Page | 184 |
| Page Count | 24 |
| Starting Page | 161 |
| ISSN | 00397881 |
| e-ISSN | 1437210X |
| DOI | 10.1055/s-2007-1000848 |
| Journal | Synthesis |
| Issue Number | 2 |
| Volume Number | 2008 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2007-12-18 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synthesis Organic Chemistry Push-pull Enamines Electrophilic Functionalizations |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
