NDLI: Temperature-controlled synthesis and luminescent properties of two novel coordination polymers modeled by hexa-carboxylate ligand derived from cyclotriphosphazene

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Temperature-controlled synthesis and luminescent properties of two novel coordination polymers modeled by hexa-carboxylate ligand derived from cyclotriphosphazene

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Temperature-controlled synthesis and luminescent properties of two novel coordination polymers modeled by hexa-carboxylate ligand derived from cyclotriphosphazene

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Liu, Chengmei Dai, Xiaomei Zhang, Tianle Li, Bao Yu, Kaichao Meng, Xianggao
Description	Author Affiliation: Li B ( School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, P. R. China. libao@mail.hust.edu.cn)
Abstract	Solvothermal reactions of hexakis(4-formylphenoxy)cyclotriphosphazene $(H_{6}L1)$ with $Cd(NO_{3})_{2}·4H_{2}O$ in H $_{2}O$ /DMF under different synthesis temperatures produced two new compounds, namely, $\{[Cd_{3}(C_{42}H_{24}O_{18}P_{3}N_{3})$ $(H_{2}O)_{7}]·xGuest\}_{n}$ (1), and $\{[Cd_{2}(C_{42}H_{24}O_{18}P_{3}N_{3})$ $(H_{2}O)_{2}]·xGuest\}_{n}$ (2). Compound 1 exhibits a novel 3D framework adopting 2,4,6-connected 3-nodal topology with the point (Schläfli) symbol $\{4^{4}·6^{2}\}\{4^{5}·6^{2}·8^{8}\}\{4\}$ constructed from the joint of neutral $Cd_{2}$ SBUs, mono-Cd ions and L1 ligands . Compound 2 reveals a 2D crystal structure exhibiting a 3,6-connected 2-nodal kgd topology with the point (Schläfli) symbol $\{4^{3}\}_{2}\{4^{6}·6^{6}·8^{3}\}$ constructed from the connection of Cd centers and L1 ligands . In these two compounds, the ligands L1 are fully deprotonated, whose six extended carboxyl arms connect six different/same metallic nodes to form high dimensional frameworks. The variable reaction temperature must be responsible for the higher coordination number and versatile coordination modes of carboxylates in 1 compared to the ones in 2, resulting in the formation of a distinct crystal structure. In the solid state, both complexes are photoluminescent (LMCT) at room temperature.
ISSN	14779226
Issue Number	7
Volume Number	42
e-ISSN	13645447
Journal	Dalton Trans.
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2013-02-21
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Carboxylic Acids Chemistry Luminescence Organometallic Compounds Organophosphorus Compounds Polymers Temperature Cadmium Crystallography, X-Ray Models, Molecular Molecular Structure Chemical Synthesis Journal Article Research Support, Non-U.S. Gov't
Content Type	Text
Resource Type	Article
Subject Domain (in MeSH)	Inorganic Chemicals Organic Chemicals Investigative Techniques Physical Phenomena Chemical Phenomena Technology, Industry, and Agriculture Environment and Public Health
Subject	Inorganic Chemistry

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